A new approach for the kinetic modeling of free radical bulk polymerization of styrene
نویسندگان
چکیده
منابع مشابه
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polymerization of styrene in presence of two monofunctional initiators is studied kinetically in an ampoule scale. polymerizations were ceased at different conversions for each ampoule while the temperature was increased almost linearly during the reaction. three different initiator mixtures were used. the first mixtures were composed of benzoil peroxide (bpo) and t-butyl perbenzoate (tbpb) wit...
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Simulation of Styrene Polymerization Reactors: Kinetic and Thermodynamic Modeling
A mathematical model for the free radical polymerization of styrene is developed to predict the steady-state and dynamic behavior of a continuous process. Special emphasis is given for the kinetic and thermodynamic models, where the most sensitive parameters were estimated using data from an industrial plant. The thermodynamic model is based on a cubic equation of state and a mixing rule applie...
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In this work, based on experimental observations and exact theoretical predictions, the kinetic scheme of RAFT polymerization is extended to a wider range of reactions such as irreversible intermediate radical terminations and reversible transfer reactions. The reactions which have been labeled as kinetic scheme are the more probable existing reactions as the theoretical point of view. The ...
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ژورنال
عنوان ژورنال: Polymer Journal
سال: 2011
ISSN: 0032-3896,1349-0540
DOI: 10.1038/pj.2011.76